1st attach the red booster cable to the red +ve of the car's battery terminal
NEXT, attach the other end of the red booster cable to the booster battery's red terminal
NEXT, attach the black end of the booster cable to the black neg terminal of the booster battery
NEXT, attach the black end of the other end of the booster to the ENGINE's LIFTING BRACKET (NOT the car battery terminal!) or the STRUT MOUNTING NUT or as per vehicle's manual
ENSURE the cable is not in danger of moving parts and the clamps are not touching any other metal
if using a 2nd car's battery, start that car's engine and run it at moderate idle speed