Watt-hours is a unit of total energy
using watt-hours as a measure instead of amp-hours (Ah) means that you can better equate batteries of different voltages and you have a universal measure of how long a battery will last given use of a appliance of a known amount of Watts independent of the voltage
Watt-hours (Wh) = Amp-hours (Ah) x Voltage = average watts used per hour x number of hours
ie. a 20W light bulb running for 1 hour uses 20Wh of energy
ie. a 12V LiFePO4 battery with a capacity of 100Ah and nominal voltage of 12.8V has an energy capacity of 1280Wh (= 12.8V x 100Ah) and this would allow a 20W device to run for 64 hours (= 1280Wh / 20W)
1Wh = 3600J = 860.4 calories = 3.4 BTU
by definition, it takes 1 calorie to heat 1g (=1mL) of water by 1degC, thus to heat 500mL water from 15degC to boiling (100degC) should require 42,500 calories = 49Wh (in reality due to less than 100% efficiency, an electric kettle will actually use around 57Wh)
by definition, BTU is the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit